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Sodium acetate

Sodium acetate
General
Chemical formula 3CO
Appearance white solid
CAS number 127-09-3 (anhydrous)
6131-90-4 (trihydrate)
Physical
Molecular weight 136.08 amu
Melting point decomposes at 597 K
(324 °C)
Boiling point n/a
Density 1.45 g/cm
Crystal structure orthorhombic
Solubility 76 g/100 g of water
Thermochemistry
ΔfH0gas -?
ΔfH0liquid  ?
ΔfH0solid  ?
S0gas, 1 bar  ?
S0liquid, 1 bar  ?
S0solid  ?
Safety
Ingestion Large doses may cause abdominal pain, nausea and vomiting.
Inhalation May cause irritation, with symptoms of coughing, sore throat, labored breathing, and chest pain.
Skin May cause irritation (redness and/or pain).
Eyes Chronic exposure may cause irritation, redness and pain.

SI units and standard conditions used unless otherwise stated.
Disclaimer and references


Sodium acetate, also known as sodium ethanoate, is used in a number of industries:

The last usage is seen in consumer heating pads. The contents (sodium acetate and water) are solid at normal temperature, but are heated in boiling water to melt the contents; after cooling, the clicking of a disk within the pad triggers the supercooled liquid to freeze and crystallise. The release of energy returns the pad to its freezing point of 54°C until it has fully solidified. The process is theoretically repeatable indefinitely, although the containing pouch will eventually break in practice.

Reactions

sodium acetate might be used as a reagent to perform the esterification with ethanol

H3C-COO- Na+ + HO-CH2-CH3 + H+ ----> H3C-COO-CH2-CH3 + H-0-H

Hence, the reaction runs with sodium acetate in excess, and because sodium acetate binds 3 water molecules, this reaction, I read only once might be possible to be performed.

Synthesis of Sodium Acetate

Sodium acetate can be obtained easily by the reaction with of acetic acid with sodium hydrogen carbonate

H3C-COOH + Na+[HCO3]- -----> H3C-COO- Na+ + H2CO3

The resulting carbonic acid hydrolyses quickly so the equilibrum is pushed to the right

Last updated: 05-27-2005 03:06:41
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