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Stereospecific

In chemistry, a stereospecific chemical reaction yields different stereoisomeric reaction products from two stereoisomeric reactants depending on the reaction conditions.

example:

The addition of dibromocarbene to cis-2-butene yields cis-2,3-dimethyl-1,1-dibromocyclopropane whereas addition of dibromocarbene to the trans isomer exclusively yields the trans cyclopropane.


Chiral synthesis is built on stereospecific reactions where also the optical activity of a chemical compound is preserved.


Related topics


References

Skell, P.S. Garner, A.Y. Journal American Chemical Society. 78, 3409 (1956)

Last updated: 10-10-2005 01:02:25
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