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# Acid rain

Acid rain is defined as rain with a pH of below 4.0 - 4.5. Normal rain has a pH of about 5.6, which is slightly acidic. This natural acidity is caused by dissolved carbon dioxide dissociating to form weak carbonic acid. 'Acid rain' is caused by sulfur from impurities in fossil fuels and nitrogen from the air combining with oxygen to form sulfur dioxide and nitrogen dioxide. These diffuse into the atmosphere and react with water to form sulfuric and nitric acids which are soluble and fall with the rain. Some hydrochloric acid is also formed.

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## Origin

The principal natural phenomenon that contribute acid-producing gases to the atmosphere are emissions from volcanoes and from biological processes that occur on the land, in wetlands, and in the oceans. The effects of acidic deposits have been detected in glacial ice thousands of years old in remote parts of the globe.

Principal human sources are industrial and power-generating plants and transportation vehicles. The gases may be carried hundreds of miles in the atmosphere before they are converted to acids and deposited.

Industrial acid rain is a substantial problem in China, Eastern Europe, Russia and areas down-wind from them. These areas all burn sulfur-containing coal to generate heat and electricity.

## Formation

A possible reaction for the production of acid rain is as follows:

$\begin{matrix} S_{(s)}+O_{2(g)}\rightarrow SO_{2(g)} \\ 2 SO_{2(g)}+O_{2(g)}\rightarrow 2 SO_{3(g)} \\ SO_{3(g)} +H_2O_{(l)}\rightarrow H_2SO_{4(aq)}\\ \end{matrix}$

Evidence for an increase in the levels of acid rain comes from analysing layers of glacial ice. These show a sudden decrease in pH from the start of the industrial revolution of 6 to 4.5 or 4. Other information has been gathered from studying organisms known as diatoms which inhabit ponds. Over the years these die and are deposited in layers of sediment on the lakes bottom. Diatoms thrive in certain pHs, so the numbers of diatoms found in layers of increasing depth give an indication of the change in pH over the years.

Since the industrial revolution, emissions of sulphur and nitrogen oxides to the atmosphere have increased. Industrial and energy-generating facilities that burn fossil fuels, primarily coal, are the principal sources of increased sulphur oxides. Occasional pH readings of well below 2.4 (the acidity of vinegar) have been reported in industrialized areas. These sources, plus the transportation sector, are the major originators of increased nitrogen oxides.

The problem of acid rain not only has increased with population and industrial growth, it has become more widespread. The use of tall smokestacks to reduce local pollution has contributed to the spread of acid rain by releasing gases into regional atmospheric circulation. Often deposition occurs a considerable distance from its formation, with mountainous regions tending to receive the most (simply because of their higher rainfall). An example of this effect is the frequent high pH of rain which falls in Scandinavia compared to the oxide levels it gives off.

There is a strong relationship between lower pH values and the loss of populations of fish in lakes. Below 4.5 virtually no fish survive, whereas levels of 6 or higher promote healthy populations. Acid in water inhibits the production of enzymes which enable trout larvae to escape their eggs. It also mobilises toxic metals such as aluminium in lakes. Aluminium causes some fish to produce an excess of mucus around their gills, preventing proper ventilation. Phytoplankton growth is inhibited by high acid levels, and animals which feed on it suffer.

Many lakes are subject to natural acid runoff from acid soils, and this can be triggered by particular rainfall patterns that concentrate the acid. An acid lake with newly-dead fish is not evidence of severe air-pollution.

Trees are harmed by acid rain in a variety of ways. The waxy surface of leaves is broken down and nutrients are lost, making trees more susceptible to frost, fungus and insects. Root growth slows and as a result less nutrients are taken up. Toxic ions are mobilised in the soil, and valuable minerals are leached away or (in the case of phosphate) become bound to clay.

The toxic ions released due to acid rain forms the greatest threat to humans. Mobilized copper has been implicated in outbreaks of diarrhoea in young children and it is thought there are links between water supplies contaminated with aluminium, causing Alzheimer's disease.

## History

Acid rain was first reported in Manchester, England which was an important city during the Industrial Revolution In 1852, Robert Angus Smith found the relationship between acid rain and atmospheric pollution . The term "acid rain" was used by him in 1872. He observed that acid rain could lead to natural destruction. Though acid rain was discovered in 1852, it wasn't until the 1970's that scientists began observing acid rain. Acid rain was a problem that would get worse....

## Solutions

In the U.S., many coal-burning power plants use flue gas desulfurisation system (FGD) to remove sulfur-containing gases from their stack gases. An example of FGD is the wet scrubber which is commonly used in the U.S. and many other countries. A wet scrubber is basically a reaction tower equipped with a fan that extracts hot smoky stack gases from a power plant into the tower. Lime or limestone in slurry form is also injected into the tower to mix with the stack gases and combine with the sulfur dioxide present. The calcium carbonate of the limestone produces pH-neutral calcium sulfate that is physically removed from the scrubber. That is, the scrubber turns sulfur pollution into industrial sulfates.

In some areas the sulfates are sold to chemical companies as gypsum when the purity of calcium sulfate is high. In others, they are placed in a land-fill.

Some people oppose regulation of power-generation, believing that power-generation and pollution are required to go together. This is false. Nuclear reactors generate less than one-millionth the toxic waste (measured by net biological effect) per watt, when wastes of both power-generation facilities are properly handled (The United States forbids nuclear recycling, so that country produces more "waste" than other countries).

An even more benign regulatory scheme involves emission trading. In this scheme, every current polluting facility is given an emissions license that becomes part of capital equipment. Operators can then install pollution control equipment, and sell parts of their emissions licenses. The main effect of this is to give operators real economic incentives to install pollution controls. Since public interest groups can retire the licenses by purchasing them, the net result is a continuously decreasing and more diffused set of pollution sources. At the same time, no particular operator is ever forced to spend money without a return of value from commercial sale of assets.